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Isotopes are a special kind of atom. Atoms with the same number of protons but different numbers of neutrons are isotopes of each other. For example, Uranium 235 and Uranium 238 are isotopes of the element uranium. They both have 92 protons in their nuclei but have differing numbers of neutrons. The nucleus of Uranium 235 has 92 protons plus 143 neutrons (92 + 243 = 235). The nucleus of Uranium 238 has 92 protons plus 146 neutrons (92 + 146 = 238).

Atom, Proton, and Neutron Briefly Defined

An atom is a tiny component of matter. An atom is 1/100,000 the width of a human hair, a human hair being one of the smallest things that we can see with our unaided eyes. In other words, if we could place 100,000 atoms side-by-side, they would span the width of a human hair, and we would barely be able to see the lot of them as a tiny dot.

An atom is composed of a nucleus surrounded by a negatively charged electron or electrons. Within the nucleus is at least one proton, a positively charged particle and, for the vast majority of elements, one or more neutrons. Protons and neutrons are similar in mass and about 1,837 times heavier than electrons.

An Example–Isotopes of the Hydrogen Atom

isotope, hydrogen isotope, protium, deuterium, tritium, neutrons
[Image source: Dirk Hünniger; Derivative work in English – Balajijagadesh; CC BY-SA 3.0 (http://creativecommons.org/licenses/by-sa/3.0)], via Wikimedia Commons) https://en.wikipedia.org/wiki/Isotope Retrieved June 11, 2017.]
This diagram shows the three naturally-occurring stable isotopes of the hydrogen atom. Protium is ordinary hydrogen gas. Its nucleus is made up of one proton (shown in red). It has no neutrons. Deuterium has one proton and one neutron (shown in black). Tritium has one proton and two neutrons. Both deuterium and tritium are rare relative to ordinary hydrogen.

The hydrogen isotopes act similarly in chemical reactions. For example, all three combine with oxygen to form water molecules. In fact, the ocean is one of the best sources of deuterium and tritium. A small fraction of water molecules in the ocean include atoms of deuterium or tritium rather than ordinary hydrogen.

[Image source: By Benjah-bmm27 – Own work, Public Domain, https://commons.wikimedia.org/w/index.php?curid=1997535 https://en.wikipedia.org/wiki/Properties_of_water Retrieved June 21, 2017]
Water molecule. This diagram shows a “ball and stick” model of the atoms that make up a water molecule. A hydrogen atom (red) bonds with two oxygen atoms (white). The colors in the diagram are arbitrary.

Isotopes Behave Similarly in Chemical Reactions

Isotopes behave similarly to other isotopes of the same element in chemical reactions because such reactions don’t depend on the properties of atomic nuclei. Rather they depend on the number and arrangement of an atom’s electrons.

Because isotopes react similarly in chemical reactions, it can be quite difficult to separate one isotope from another. This creates a challenge when separating isotopes that are radioactive from non-radioactive isotopes of the same element. Scientists have developed separation techniques that are used in both creating fuel for both nuclear bombs and nuclear reactors.

Isotopes Vary in Weight and Radioactivity

tritium exit sign, green exit sign, tritium gas green glow
Exit sign with the greenish glow of the sort given off by tritium. [Image source: Alton – Own work, CC BY 3.0, https://commons.wikimedia.org/w/index.php?curid=3430712 https://en.wikipedia.org/wiki/Exit_sign Retrieved June 21, 2017.]
Due to differences in their nuclei, the three hydrogen isotopes vary primarily in their weight and in their radioactive properties. Ordinary hydrogen, with no neutrons, is lightest, followed by deuterium, and then tritium. Ordinary hydrogen is not naturally radioactive. Deuterium is not naturally radioactive but is useful in nuclear reactors due to its vulnerability to nuclear fission. Tritium is naturally radioactive and gives off a greenish glow. This glow is put to use in creating the light of some Exit signs.


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